Ammonium Hydrogen Difluoride
Fluoride Fluoropolymers Hydrofluoric Acid/Foaming Agent Fluoride Salt Fluorine-Containing

Ammonium Hydrogen Difluoride

Duxiu Chemical

Specifications

HS Code

767432

Chemical Formula NH4HF2
Molar Mass 57.04 g/mol
Appearance White crystalline solid
Odor Pungent
Density 1.5 g/cm³
Melting Point 125.6 °C
Boiling Point 239.5 °C
Solubility In Water Soluble
Ph Of Aqueous Solution Acidic
Hazard Class Corrosive

As an accredited Ammonium Hydrogen Difluoride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

Packing & Storage
Packing Ammonium Hydrogen Difluoride in 5 - kg bags for safe storage and handling.
Storage Ammonium hydrogen difluoride should be stored in a cool, dry, well - ventilated area. Keep it away from heat sources, open flames, and incompatible substances like strong acids and alkalis. Store in tightly - sealed containers made of corrosion - resistant materials to prevent leakage, as it is corrosive and can emit harmful fumes upon decomposition.
Shipping Ammonium Hydrogen Difluoride is shipped in well - sealed, corrosion - resistant containers. Due to its corrosive nature, it requires special handling during transit, following strict safety regulations to prevent leaks and ensure safe delivery.
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Ammonium Hydrogen Difluoride
General Information
Historical Development
Ammonium Hydrogen Difluoride (Ammonium Hydrogen Difluoride), the rise of its material, began with research and development. At the beginning, everyone explored various chemical substances, hoping to obtain new substances to meet all needs.
This ammonium fluoride difluoride has been studied over the years, and its properties have gradually become clear. In the past, scholars devoted themselves to investigation, analyzing its composition and distinguishing its characteristics from the micro-signs. Beginning to know its unique nature, it can be used in industrial things to develop its effectiveness.
With the passage of time, the deeper the research, the more widely used. From the beginning, it was only known to the minority, and later it emerged in the chemical industry, helping manufacturing and promoting the progress of technology. Its historical evolution is due to the unremitting efforts of researchers of various generations, which has made it a place in the industry today and added a brilliant chapter to the development of chemical products.
Product Overview
"Ammonium Hydrofluoride"
Ammonium hydrofluoride is a wonderful chemical product. Its English name is Ammonium Hydrogen Difluoride. This substance is white crystalline and has deliquescence. At room temperature, it has a certain stability, but when heated, it is divided and releases hydrogen fluoride and other gases.
Its use is quite extensive. In the chemical industry, it is often used as an etchant, which can refine the surface of glass and give it a unique texture. In the metallurgical industry, it can help the decomposition of ores and improve the efficiency of metal refining.
The preparation method is mostly obtained by neutralizing hydrofluoric acid and ammonia. However, it is corrosive, and when operating, it must be carefully protected to avoid personal injury. This is the general description of ammonium hydrogen fluoride.
Physical & Chemical Properties
In the field of chemical industry, there is a thing called Ammonium Hydrogen Difluoride. This material is very different, related to physical and chemical properties, and cannot be ignored.
Its quality is pure and close to prime, often in a crystalline state, and it looks bright. It belongs to salts, which are easily soluble in water, and when dissolved, it is accompanied by heat change. In case of alkali, it should produce ammonium fluoride and water. This is the common way of neutralizing acid and base.
Its physical characteristics, the melting point is quite low, and under moderate temperature, it can be converted into liquid. The density also has a certain number, which is related to its state of floating in matter. Chemical activity is quite high, and it is corrosive to various metals. When used, it should be used with caution. However, because of its characteristics, it is widely used in the etching industry and glass processing, and is an indispensable material for workers. Knowing its physical and chemical quality, we can make good use of it, avoid its harm and pursue its benefits.
Technical Specifications & Labeling
There is a product today called Ammonium Hydrogen Difluoride. Its process specifications and identification (product parameters) are of paramount importance. The process specifications of this product need to be carefully studied and prepared, from the selection of raw materials to the control of reaction conditions, all must be accurate. Such as material ratio, temperature control, reaction time, etc., are all key.
And the identification (product parameters), when specifying its physical and chemical characteristics, such as properties, purity geometry. The purity must reach a specific standard, and the impurity content must be strictly controlled within the limit. And its use and storage method should be clearly indicated. Storage should be in a dry and cool place to prevent mixing with other substances from causing change. In this way, we can obtain the essentials of this product's process specifications and identification (product parameters) to ensure its quality and application effectiveness.
Preparation Method
The method of making ammonium hydrogen fluoride (Ammonium Hydrogen Difluoride) is related to the raw materials and production process, reaction steps and catalytic mechanism, which is really important. The raw materials are often hydrofluoric acid and ammonia. First prepare an appropriate amount of hydrofluoric acid in a special container, and slowly introduce ammonia gas according to the precise ratio. When the two meet, a compound reaction starts.
During the reaction, temperature control and pressure control are extremely critical. If the temperature is too high or too low, it will affect the purity and yield of the product. The reaction steps need to be gradual. The reaction is intense at the beginning, and then gradually stabilizes. After the reaction is complete, after fine treatment, impurities are removed to obtain pure ammonium hydrogen fluoride.
As for the catalytic mechanism, the use of a specific catalyst can promote the reaction to accelerate and improve efficiency. In this way, high-quality ammonium hydrogen fluoride products are prepared in an exquisite way, which have important uses in many fields of chemical industry.
Chemical Reactions & Modifications
"On the Transformation of Ammonium Hydrofluoride"
Ammonium hydrofluoride is also a chemical thing. The wonders of its transformation are related to many things. Looking at its reaction and combining with other things, it often shows a specific appearance. In a specific environment, either heat generation or discoloration are signs of chemical changes.
As for the change of its chemical properties, temperature and pressure can be controlled. When the temperature increases, the reaction rate may increase sharply, and the movement of molecules intensifies, which prompts the change of speed. Changes in pressure can also make the reaction different.
Ammonium hydrofluoride encounters water, or dissociates into ions, participating in various reactions. When it encounters alkali, it neutralizes acid and base, forming salt and water. These reactions depend on their chemical properties.
If you want to make good use of ammonium hydrogen fluoride, you must study these chemical changes and chemical properties in detail. Only by understanding its laws can you use it properly in various fields of industry and scientific research, avoid harm and seek profit, and achieve the expected effect.
Synonyms & Product Names
"Ammonium Hydrogen Difluoride"
Ammonium Hydrogen Difluoride, in the field of chemical industry, has a variety of nicknames and trade names. Its name is acid ammonium fluoride, which is named according to its chemical composition and properties. It is covered because it contains ammonium roots and has acidic fluorination characteristics.
It is also called ammonium hydrofluoride, which is also based on its molecular structure and the part containing hydrogen difluoride, so it gets this name. As for the trade name, it varies depending on the manufacturer and use. It may be sold because of its high efficiency and purity, and it is named such as "high-purity ammonium hydrofluoride" to recognize its quality.
Such aliases and trade names, although different, refer to ammonium fluorohydride. Chemical researchers and practitioners need to carefully investigate their differences and clarify their essence in order to be correct in practical application and research.
Safety & Operational Standards
"Ammonium Hydrogen Difluoride Product Safety and Operation Specifications"
Ammonium Hydrogen Difluoride (Ammonium Hydrogen Difluoride) is also a chemical product. Its unique nature is related to safety and operation standards, and cannot be ignored.
In terms of safety, this substance is corrosive, and if it touches the skin, it can cause burns. Therefore, when handling, protective gear is indispensable. Wearing protective clothing, if the armor protects the body, it will prevent its erosion; wearing protective gloves, it is like a shield in the hand to protect against its harm; wearing a protective mask on the face, it is still in front of the barrier to protect the facial features.
As for the operating code, it is suitable for a well-ventilated place. If the breeze comes slowly, the turbid gas will dissipate, avoiding the risk of accumulation of harmful gases. When taking it, the method should be stable and accurate, and take it according to the quantity. Don't be greedy and don't abuse it. After use, store it properly, and place it in a cool and dry place. If you hide treasures, prevent it from deteriorating and damaging.
Furthermore, if you accidentally touch it, rinse it with a lot of water quickly, such as a torrent to clean up the stains and remove its harmful substances. If the situation is critical, seek medical treatment urgently, and do not delay for a while.
In short, the safety and operating standards of ammonium hydrofluoride must be kept in mind, and it should be done with caution. Only by walking on thin ice can you avoid disaster.
Application Area
Ammonium hydrogen fluoride is also a wonderful product of chemistry. Its application field is quite extensive. In the art of etching, glass, silicon, etc. rely on its work. With its ability to work with various objects, carve delicate textures, making utensils very delicate.
In the world of metallurgy, it is also indispensable. It can help purify metals, remove impurities and retain essence, making metals have better texture and better performance.
In the process of chemical synthesis, it is often a booster. Participate in a variety of reactions, promote the process of synthesis, and produce novel and useful substances.
Looking at its uses, it exhibits unique capabilities in many fields. It is a valuable treasure in the chemical world, contributing to the prosperity of many technologies and industries.
Research & Development
The chemical industry is changing with each passing day, and many new substances have emerged. Now, Ammonium Hydrogen Difluoride is of great significance in the process of scientific research and development.
At the beginning of research, everyone explored its properties. After repeated experiments, its chemical characteristics were known, and it showed unique effects in specific reactions. It can participate in a variety of chemical changes, providing opportunities for the synthesis of new qualities.
When developing, consider its application domain. In the manufacture of materials, it can optimize the texture and increase its performance. In the electronics industry, it also has wonderful uses to help refine components.
However, the road to development is not smooth sailing. It is necessary to solve production problems, control its costs, and take into account environmental impact. After unremitting research, the technology has gradually matured and the application has become wider. In the future, it is hoped that it will shine in more fields and promote the progress of scientific research and industry.
Toxicity Research
"On the Toxicity of Ammonium Hydrofluoride"
Ammonium hydrofluoride is also a chemical product. Its unique nature, the investigation of toxicity, is related to the well-being of everyone and the stability of the environment.
Today's detailed inspection of this agent, its corrosive, touch the skin, such as fire burning the body, pain is unbearable, and can cause deep tissue damage, difficult to quickly heal. If you are not careful to enter the eyes, the eyes will be painful and tears will flow, and the vision will be unclear; in severe cases, it may cause blindness, which is deeply harmful.
Inhalation of its volatile gas, damage to the respiratory tract, chest tightness and asthma, cough, and even can cause lung diseases, endangering life.
Although it is a chemical agent, its toxicity cannot be underestimated. During the research and use, it is necessary to strictly abide by the procedures, prepare protective equipment, and be cautious in order to avoid disasters, protect your life and safety, and protect the environment from its contamination.
Future Prospects
Today there is a name Ammonium Hydrogen Difluoride, which has a wide range of uses in industry. Looking at the current situation, its preparation process is becoming more and more exquisite, but it can still be used.
My generation expects that in the future, the preparation method will reach a new high, the energy consumption will be greatly reduced, and the yield will surge. In this way, the cost will be reduced, and the competitiveness in the market will be stronger. And its application field is expected to be expanded to an unprecedented field, such as the research of high-tech materials, which will contribute to the advancement of science and technology.
Furthermore, environmental protection should not be ignored. In the future production, we must pay attention to the treatment of waste to reduce its harm to the environment, so as to achieve sustainable development. In this way, Ammonium Hydrogen Difluoride will be able to shine in the future and make infinite contributions to the world.
Where to Buy Ammonium Hydrogen Difluoride in China?
As a trusted Ammonium Hydrogen Difluoride manufacturer, we deliver: Factory-Direct Value: Competitive pricing with no middleman markups, tailored for bulk orders and project-scale requirements. Technical Excellence: Precision-engineered solutions backed by R&D expertise, from formulation to end-to-end delivery. Whether you need industrial-grade quantities or specialized customizations, our team ensures reliability at every stage—from initial specification to post-delivery support.
Frequently Asked Questions

As a leading Ammonium Hydrogen Difluoride supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.

What is Ammonium Hydrogen Difluoride?
Ammonium hydrogen fluoride (Ammonium Hydrogen Difluoride) is a chemical substance. It has a specific chemical composition and properties. The chemical formula of this substance is $NH_ {4} HF_ {2} $, which is composed of ammonium ions ($NH_ {4 }^{+}$) and hydrogen fluoride ions ($HF_ {2 }^{-}$).
Ammonium hydrogen fluoride often has a white crystalline appearance and is corrosive. It is widely used in the industrial field. First, it can react with silica in the glass in the glass etching process to precisely etch the desired pattern or texture. Second, it can be treated on the metal surface to clean the metal surface, remove oxides and impurities, and lay a good foundation for subsequent coating, electroplating and other processes. Furthermore, in some chemical synthesis reactions, it is used as a fluorinating agent to introduce fluorine atoms into the compound structure.
However, this substance is dangerous, its corrosiveness is strong, and contact with the human body can cause burns. If inadvertently inhaled or ingested, it will also damage the respiratory tract, digestive tract and other human organs. Therefore, when using and storing, it is necessary to follow strict safety procedures, and protective measures are essential, such as wearing protective gloves, goggles, gas masks, etc. Storage should be in a dry, well-ventilated place, away from fire sources and flammable substances, and should be stored separately from other chemicals to prevent dangerous chemical reactions. In this way, ammonium hydrogen fluoride can be used rationally to avoid potential hazards.
What are the main uses of Ammonium Hydrogen Difluoride?
Ammonium Hydrogen Difluoride (Ammonium Hydrogen Difluoride) has a wide range of uses and is useful in all kinds of industrial things.
First, it is very useful in the industry of glass etching. Glass objects, if they want to form delicate patterns and clear patterns, often rely on ammonium hydrogen fluoride. It can react with silica, the main component of glass, to slowly etch off part of the glass, so that the desired shape can be displayed on it. For example, when carving glass, craftsmen use ammonium hydrogen fluoride as an agent and carefully perform techniques. On the glass, beautiful patterns are born, or for flowers and birds, or for characters, which are lifelike, enhancing the beauty of glass. It is widely used in the field of decoration and adding elegance to residences and buildings.
Second, it is also indispensable for the treatment of metal surfaces. Metal products, in order to prevent rust and increase their adhesion to paint, often need to be pretreated. Ammonium hydrogen fluoride can remove rust and impurities on the metal surface, making the metal surface clean and smooth, and subsequent painting, electroplating and other processes can be smooth. The metal treated by this treatment is rust-proof and durable, and the appearance is also good. For example, auto parts, mechanical parts, etc., are all improved due to their quality.
Furthermore, it is also a commonly used raw material in the process of chemical synthesis. Ammonium hydrogen fluoride is often the starting material for the preparation of many fluorine-containing compounds. Chemists use it as a basis and react delicately to obtain various chemicals with special properties, either with strong stability or unique reactivity, which are used in medicine, pesticides, electronic materials and many other fields.
In addition to wood preservatives, ammonium hydrogen fluoride also plays a role. Wood is easily infested and decayed. Treated with ammonium hydrogen fluoride, it can penetrate between wood fibers, inhibit microbial growth, prevent pest erosion, prolong wood life, and keep wood usable for a long time in construction, furniture, etc.
In summary, ammonium hydrogen fluoride has its unique functions in all branches of industry, which is an important help for the development of many industries.
What are the precautions for Ammonium Hydrogen Difluoride during use?
Ammonium Hydrogen Difluoride (Ammonium Hydrogen Difluoride) is also a corrosive chemical. When using, many things must not be ignored.
First protection. Wear appropriate protective clothing, such as corrosion-resistant clothing and gloves, to prevent it from touching the skin and causing burns to the skin. Also wear protective glasses or masks to cover it or splash it into the eyes, damaging the eyes.
The operating environment is also important. It is suitable for well-ventilated places. Because it is used in the middle or releases harmful gases, good ventilation can drive it away, so as not to gather in the room and harm the person.
Furthermore, the use of this material must follow the standard steps. When taking it, the action should be slow and careful to prevent it from spilling. If it is accidentally spilled, dispose of it as soon as possible according to emergency methods. First isolate the scene, and prohibit unrelated people from arriving; then cover it with appropriate materials, collect it and discard it properly.
Storage is also exquisite. When placed in a cool, dry and ventilated place, and away from fire and heat sources, it should not be stored on the same level as alkalis and oxidizing agents, for fear of chemical reactions and danger.
After use, the utensils used must be washed and dried to prevent residual erosion devices, and to ensure the safety of the next use.
All these things should be paid attention to when using ammonium fluoride hydrogen, and be sure to follow them, so that the security will be safe.
What are the Physical and Chemical Properties of Ammonium Hydrogen Difluoride?
Ammonium hydrogen fluoride (Ammonium Hydrogen Difluoride), its unique physical and chemical properties, is described in detail by you today.
This substance is often colorless and transparent in appearance, its texture is brittle, and it is easily deliquescent in air. In terms of its melting point, it is about 125.6 ° C, and its boiling point is 240 ° C.
When it comes to solubility, it is easily soluble in water, and when dissolved, it will release heat, and the aqueous solution is acidic. This is because it will ionization in water, resulting in ammonium ions ($NH_ {4 }^{+}$) and hydrogen fluoride ions ($HF_ {2 }^{-}$), Further hydrolysis of hydrogen fluoride ions makes the solution acidic.
Its chemical properties are active. When exposed to acid, it will decompose and release hydrogen fluoride gas, which is corrosive and irritating, and is very harmful. When exposed to alkali, it will neutralize and produce corresponding salts and water. For example, it reacts with sodium hydroxide to generate sodium fluoride, water and ammonia.
Ammonium hydrogen fluoride is also corrosive, and has a strong irritation and corrosive effect on human skin, eyes and respiratory tract. If accidentally exposed to the skin, it can cause skin burns, redness, swelling and pain; if it enters the eye, it can seriously damage vision.
is widely used in industrial fields. It is often used for glass etching, which can form specific patterns and textures on the glass surface. In metal surface treatment, it can remove metal surface oxides and improve the adhesion of metals and coatings. It is also used to produce other fluorides.
When using this product, it is necessary to strictly follow the safety operating procedures and take protective measures to avoid danger.
What are the production methods of Ammonium Hydrogen Difluoride?
Ammonium Hydrogen Difluoride (Ammonium Hydrogen Difluoride), that is, ammonium hydrogen fluoride, there are two common methods for its preparation.
One is to use anhydrous hydrofluoric acid and liquid ammonia as raw materials. First take a clean reactor and slowly inject anhydrous hydrofluoric acid into it. This hydrofluoric acid is highly corrosive and needs to be operated with caution. After low temperature and sufficient stirring, liquid ammonia is introduced at a specific rate. When liquid ammonia meets hydrofluoric acid, the two quickly combine, and the following reaction occurs: $HF + NH_ {3}\ longrightarrow NH_ {4} HF_ {2} $. In this process, the temperature and the rate of ammonia introduction are the key. If the temperature is too high, the product is easy to decompose; if the ammonia is introduced too fast, the reaction is difficult to fully proceed. After the reaction is completed, the pure ammonium hydrogen fluoride product can be obtained through cooling, crystallization, separation, drying and other processes.
Second, ammonium fluoride solution and hydrofluoric acid are used as raw materials. In the reaction vessel, an appropriate amount of ammonium fluoride solution is filled, and hydrofluoric acid is added dropwise, and at the same time, stirring is continued to promote the uniform mixing and reaction of the two. The chemical reaction formula is: $NH_ {4} F + HF\ longrightarrow NH_ {4} HF_ {2} $. This process requires close monitoring of the pH value of the solution and the reaction temperature to ensure that the reaction proceeds smoothly in the direction of generating ammonium hydrogen fluoride. After the reaction is completed, the mixture is evaporated and concentrated to crystallize the ammonium hydrogen fluoride, and then filtered, washed and dried to obtain the finished product.
These two methods have their own advantages and disadvantages. Although the former raw material anhydrous hydrofluoric acid and liquid ammonia react directly, both are dangerous and require extremely high equipment and operation requirements. The latter raw materials are relatively easy to obtain and operate. However, precise control of reaction conditions is required to ensure product purity and quality.